Consider the following statements with reference to the Periodic Table of chemical elements:
1. Ionisation potential gradually decreases along a period.
2. In a group of elements, electron affinity decreases as the atomic weight increases.
3. In a given period, electronegativity decreases as the atomic number increases.
Which of these statement(s) is/are correct?
Correct Answer: Option B
Explanation
1. Statement 1: Ionisation potential (or ionization energy) generally *increases* along a period in the Periodic Table from left to right, because the effective nuclear charge increases, holding electrons more tightly. (Incorrect)
2. Statement 2: In a group of elements, as atomic weight (and atomic size) increases down the group, the outermost electron is further from the nucleus and shielded by inner electrons. This generally leads to a *decrease* in electron affinity (energy released when an electron is added). (Correct)
3. Statement 3: Electronegativity, the tendency of an atom to attract bonding electrons, generally *increases* along a period as the atomic number increases, due to increasing effective nuclear charge. (Incorrect)
4. Therefore, only statement 2 is correct.
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